A diamantane-4,9-dicarboxylate based UiO-66 analogue: challenging larger hydrocarbon cage platforms

Vasily Gvilava; Maximilian Vieten; Robert Oestreich; Dennis Woschko; Moritz Steinert; Ishtvan Boldog; Roman Bulánek; Natalie A. Fokina; Peter R. Schreiner; Christoph Janiak

doi:10.1039/D2CE01170K

A diamantane-4,9-dicarboxylate based UiO-66 analogue: challenging larger hydrocarbon cage platforms†

Vasily Gvilava,

^a Maximilian Vieten,^a Robert Oestreich,

^a Dennis Woschko,

^a Moritz Steinert,^a Ishtvan Boldog,

*^a Roman Bulánek,

^b Natalie A. Fokina,^c Peter R. Schreiner

^cd and Christoph Janiak

*^a

Author affiliations

* Corresponding authors

^a Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, D-40204 Düsseldorf, Germany
E-mail: janiak@uni-duesseldorf.de

^b Department of Physical Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentska 573, 532 10 Pardubice, Czech Republic

^c Institute of Organic Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17, 35392 Giessen, Germany

^d Center for Materials Research (ZfM), Heinrich-Buff-Ring 16, 35392 Giessen, Germany

Abstract

The first use of a bulky barrel-shaped ligand is demonstrated in HHUD-3, with accessible porosity only feasible for a defect structure. With 35%+ missing linker defects and S_BET = 890 m²g⁻¹ (N₂), HHUD-3 features higher CH₄ but lower CO₂ and H₂ adsorption than UiO-66.

CrystEngComm

A diamantane-4,9-dicarboxylate based UiO-66 analogue: challenging larger hydrocarbon cage platforms†

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A diamantane-4,9-dicarboxylate based UiO-66 analogue: challenging larger hydrocarbon cage platforms

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